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Class 12 Science (PCM)

Physics Part 2

Dual Nature of Radiation and Matter

Dual Nature of Radiation and Matter

Study Action Plan (Sorted by Difficulty)
De Broglie Wavelength of Accelerated Electron
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Effect of Collector Potential on Photocurrent
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Effect of Frequency on Stopping Potential
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Effect of Intensity on Photocurrent
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Einstein's Photoelectric Equation
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Experimental Laws of Photoelectric Emission
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Intensity in Photon Picture
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Matter Waves and De Broglie Wavelength
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Maxwell's Equations and Wave Nature of Light
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Photoelectric Effect
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Photoelectric Graphs and Slopes
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Photon Picture of Radiation
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Planck's Constant and Photon Energy
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Stopping Potential and Kinetic Energy
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Threshold Frequency and Work Function
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Wave-Particle Duality
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Experimental Setup for Photoelectric Effect
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Cathode Rays and Electron Discovery
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Failure of Classical Wave Theory
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Hertz, Hallwachs and Lenard Observations
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Types of Electron Emission
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Electron Emission and Work Function
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De Broglie Hypothesis
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Learning Objectives

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  • Understand the dual nature of radiation and matter.
  • Explain the photoelectric effect and its significance in physics.
  • Calculate the work function and threshold frequency for various materials.
  • Analyze the relationship between stopping potential and maximum kinetic energy of emitted electrons.
  • Apply the concepts of Planck's constant and de Broglie wavelength in problem-solving.

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Revision Notes & Summary

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Chapter 11: Dual Nature of Radiation and Matter

11.1 Introduction

  • The wave nature of light was established through Maxwell's equations and Hertz's experiments.
  • Key discoveries include X-rays by Roentgen (1895) and the electron by J.J. Thomson (1897).
  • Discharge tubes showed that electric discharge through gases at low pressure could produce cathode rays.

11.2 Key Concepts

Physical Quantities

Physical QuantitySymbolDimensionsUnitRemarks
Planck's constanth[ML²T⁻¹]JsE = hv
Stopping potentialV₀[ML²T⁻³A⁻¹]VeVo - Kmax
Work functionФ₀[ML²T⁻²]J; eVKₘₐₓ = E - Ф₀
Threshold frequencyV₀[T⁻¹]Hzv = /h
de Broglie wavelengthA[L]mA = h/p

11.3 Points to Ponder

  1. Free electrons in metals move in a constant potential but require additional energy to escape.
  2. Electrons have a distribution of energies at a given temperature, differing from Maxwell's distribution due to Pauli's exclusion principle.
  3. The work function is the minimum energy required for an electron to escape the metal.
  4. Energy absorption during light-matter interaction occurs in discrete units of hv.
  5. The stopping potential's independence of intensity is crucial for distinguishing between wave and photon models of the photoelectric effect.
  6. The de Broglie wavelength has physical significance, while phase velocity does not; group velocity equals the particle's velocity.

11.4 Experimental Study of Photoelectric Effect

  • Setup: An evacuated glass tube with a photosensitive plate and an anode.
  • Process: Monochromatic light strikes the photosensitive plate, emitting electrons collected by the anode.
  • Measurements: Current (μA) and potential difference (V) are monitored.

11.5 Observations on Photoelectric Effect

  • Maximum kinetic energy of photoelectrons varies linearly with frequency, independent of intensity.
  • No emission occurs below the threshold frequency, regardless of intensity.
  • Emission starts instantaneously (~10⁻⁹ s) when frequency exceeds the threshold.

11.6 Examples

  • Example 11.1: Photon energy and number of photons emitted by a laser.
  • Example 11.2: Calculating threshold frequency and wavelength based on work function and stopping potential.

11.7 Exercises

  1. Calculate maximum kinetic energy and stopping potential for caesium with given frequency.
  2. Determine the threshold frequency and wavelength for various metals and light conditions.
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Practice Test – MCQs, True/False

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Multiple Choice Questions

A.

Because it assumes energy is absorbed continuously over time.

B.

Because it assumes energy is absorbed in discrete packets.

C.

Because it assumes light has no energy.

D.

Because it assumes electrons cannot escape from the metal surface.
Correct Answer: A

Solution:

Classical wave theory assumes that energy is absorbed continuously, which implies that higher intensity should increase the energy absorbed by electrons, thus increasing their kinetic energy. This contradicts the observed independence of kinetic energy from intensity.

Chapter Concept:

Failure of Classical Wave Theory

A.

The number of emitted electrons per second increases.

B.

The maximum kinetic energy of emitted electrons increases.

C.

The stopping potential decreases.

D.

The work function of the metal increases.
Correct Answer: B

Solution:

Increasing the frequency of the incident light increases the maximum kinetic energy of the emitted electrons, as described by Einstein's photoelectric equation.

Chapter Concept:

Intensity in Photon Picture

A.

The kinetic energy is directly proportional to the intensity of light.

B.

The kinetic energy is independent of the frequency of light.

C.

The kinetic energy is directly proportional to the frequency of light minus the work function.

D.

The kinetic energy is inversely proportional to the frequency of light.
Correct Answer: C

Solution:

According to Einstein's photoelectric equation, the maximum kinetic energy of photoelectrons is given by Kmax=hν−Φ0K_{\text{max}} = h\nu - \Phi_0, where hh is Planck's constant, ν\nu is the frequency of the incident light, and Φ0\Phi_0 is the work function of the metal.

Chapter Concept:

Wave-Particle Duality

A.

A discharge tube with only an electric field applied

B.

A discharge tube with only a magnetic field applied

C.

A discharge tube with mutually perpendicular electric and magnetic fields applied

D.

A discharge tube with no fields applied
Correct Answer: C

Solution:

J.J. Thomson used a discharge tube with mutually perpendicular electric and magnetic fields to determine the specific charge (e/m) of cathode ray particles, proving their universality and identifying them as electrons.

Chapter Concept:

Cathode Rays and Electron Discovery

A.

h/eh/e

B.

e/he/h

C.

h⋅eh \cdot e

D.

1/h1/h
Correct Answer: A

Solution:

The slope of the stopping potential vs frequency graph is given by h/eh/e, where hh is Planck's constant and ee is the charge of an electron.

Chapter Concept:

Photoelectric Graphs and Slopes

A.

Photoelectric effect

B.

Compton effect

C.

Interference

D.

Electron emission
Correct Answer: C

Solution:

Interference is a phenomenon that demonstrates the wave nature of light, as it involves the superposition of light waves.

Chapter Concept:

Wave-Particle Duality

A.

The energy decreases.

B.

The energy remains the same.

C.

The energy increases.

D.

The energy becomes zero.
Correct Answer: C

Solution:

The energy of a photon is given by E=hcλE = \frac{hc}{\lambda}, where hh is Planck's constant, cc is the speed of light, and λ\lambda is the wavelength. As the wavelength decreases, the energy increases.

Chapter Concept:

Planck's Constant and Photon Energy

A.

The photoelectric current is independent of the intensity of the incident light.

B.

The photoelectric current decreases with increasing intensity of the incident light.

C.

The photoelectric current increases linearly with the intensity of the incident light.

D.

The photoelectric current is inversely proportional to the intensity of the incident light.
Correct Answer: C

Solution:

The photoelectric current is directly proportional to the number of photoelectrons emitted per second, which in turn is directly proportional to the intensity of the incident light. Therefore, the photoelectric current increases linearly with the intensity of the incident light.

Chapter Concept:

Experimental Laws of Photoelectric Emission

A.

The existence of a threshold frequency for photoelectric emission.

B.

The instantaneous emission of photoelectrons.

C.

The independence of maximum kinetic energy of photoelectrons from the intensity of light.

D.

The variation of photoelectric current with the intensity of light.
Correct Answer: D

Solution:

The classical wave theory predicts that energy is absorbed continuously, which should make the maximum kinetic energy of photoelectrons dependent on the intensity of light. However, the photoelectric effect shows that the maximum kinetic energy is independent of intensity, which cannot be explained by wave theory.

Chapter Concept:

Failure of Classical Wave Theory

A.

UV light enhances sparks in a detector loop.

B.

UV light discharges a negatively charged zinc plate.

C.

Photoelectric current is studied using an evacuated tube.

D.

Electrons are emitted from metals when heated to high temperatures.
Correct Answer: B

Solution:

Wilhelm Hallwachs observed that ultraviolet light discharges a negatively charged zinc plate, indicating the emission of electrons.

Chapter Concept:

Hertz, Hallwachs and Lenard Observations

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True or False

Correct Answer: True

Solution:

J.J. Thomson used perpendicular electric and magnetic fields to determine the charge-to-mass ratio (e/m) of cathode ray particles, showing their universality and identifying them as electrons.

Chapter Concept :

Cathode Rays and Electron Discovery

Correct Answer: False

Solution:

The photoelectric effect requires that the frequency of the incident light be above a certain threshold frequency specific to the material, regardless of the intensity of the light.

Chapter Concept :

Photoelectric Effect

Correct Answer: False

Solution:

The photocurrent increases with the positive collector potential until it saturates when all emitted photoelectrons are collected.

Chapter Concept :

Effect of Collector Potential on Photocurrent

Correct Answer: True

Solution:

De Broglie's hypothesis states that matter exhibits wave-like properties, with the wavelength λ\lambda given by the formula λ=hp\lambda = \frac{h}{p}, where hh is Planck's constant and pp is the momentum of the particle.

Chapter Concept :

De Broglie Hypothesis

Correct Answer: True

Solution:

The photoelectric effect shows that light interacts with matter as if it is composed of particles called photons, each carrying a quantum of energy E=hνE = h\nu, where hh is Planck's constant and ν\nu is the frequency of light. This interaction supports the particle nature of light.

Chapter Concept :

Wave-Particle Duality

Correct Answer: True

Solution:

Einstein's photoelectric equation states that the maximum kinetic energy of photoelectrons depends on the frequency of the incident light and not on its intensity. This is because the energy of each photon is determined by its frequency, and increasing the intensity only increases the number of photons, not their energy.

Chapter Concept :

Einstein's Photoelectric Equation

Correct Answer: True

Solution:

The potential difference can be varied to study how it affects the photocurrent, as it influences the attraction of emitted electrons towards the collector plate.

Chapter Concept :

Experimental Setup for Photoelectric Effect

Correct Answer: True

Solution:

The threshold frequency is indeed the minimum frequency required for photoelectric emission, as it provides the necessary energy to overcome the work function of the metal.

Chapter Concept :

Threshold Frequency and Work Function

Correct Answer: True

Solution:

The stopping potential is directly related to the maximum kinetic energy of the emitted electrons, as given by the equation eV0=KmaxeV_0 = K_{\text{max}}, where V0V_0 is the stopping potential and KmaxK_{\text{max}} is the maximum kinetic energy.

Chapter Concept :

Stopping Potential and Kinetic Energy

Correct Answer: False

Solution:

Einstein's photoelectric equation indicates that the maximum kinetic energy of the emitted photoelectrons is independent of the intensity of the incident light and depends linearly on the frequency of the incident radiation.

Chapter Concept :

Einstein's Photoelectric Equation

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